DragonFly LIBS Elemental Analysis System
DragonFlyIt is the only derivative company of the European Engineering Technology Center (CEITEC)LightigoThe product model launched by the company, parallel to FireFly, aims to achieve the strongest universality by supporting expansion and research-oriented design, allowing users to fully enjoy the strongest advantages of LIBS technology
Dragonfly can achieve excellent detection results for samples that are usually difficult to detect, such as C element in steel, F element in geotechnical materials, Cl element in concrete materials, Li element in batteries, etc.
DragonFlyFor flexible and easily expandable modular design, it features a vacuum reaction chamber with automatic continuous control ranging from 1 to 1300 mbar and automatic laser pulse wavelength switching function; In addition, a UV vacuum module can be optionally selected to solve the special situation of multiple spectral lines interfering with each other in the visible light region. DragonFly supports flexible customization, such as dual excitation, multi excitation schemes, and multi optical path acquisition. Please contact us to discuss and work together with you to achieve the most cost-effective and targeted configuration solution.
application area
l Element detection of plants, soil, geology, metals, plastics, and biomaterials;
l Element distribution mapping;
l Multi layer profile element measurement;
l The stress response of harmful metals/heavy metals in animals and plants;
l Marker and nanoparticle detection
main features
l 1-1300 mbarVacuum reaction chamber;
l Blowing module and active suction module;
l 3Automatic axis movement control panel;
l Microscopic sample observation and independent illumination of four circular segments;
l Automatic adjustment of laser focusing spot;
l 8Channel built-in digital delay generator;
l Gas blowing and gas suction adapter;
l Single excitation/dual excitation DPSS laser;
l The fastest measurement speed is 100Hz;
l Echelle/Czerny-Turnera spectrometer;
l iCCD/EMCCD/SCMOS/CMOSDetector optional
Instrument parameters
DragonFlyThe standard configuration options are shown in the table below. The main configuration can be selected according to specific needs and budget to achieve optimal cost-effectiveness.
DragonFly supports flexible customization. Please contact us to discuss your configuration plan.
sample |
Sample volume |
Maximum 80 × 80 × 50mm (sample can be irregular in shape) |
Sample holder |
Suitable for irregular samples: Universal clamp type sample holder Suitable for standard compression samples: 12 × 12 mm | 2 × 30 mm | 1 × 50 mm |
|
Electric control sample table |
Mobile range (X × Y × Z) |
60 × 80 × 50 (X × Y × Z) mm |
Mobile resolution |
0.08 μm (Micro shift/5 μ m (standard): |
|
Moving speed |
6 mm/s |
|
Sample observation |
Forward observation camera |
CMOS (Up to 55 fps, field of view range: 1.5 mm, |
Lateral observation camera |
CMOS (Up to 55 fps, field of view range: 80 mm: |
|
lighting |
LEDCircular lighting, 4-stage independent control |
|
Laser focusing |
lens |
Air medium achromatic coupling lens, focal length 30 mm |
Spot size |
Automatic adjustment range:10–150 μm |
|
Laser |
Standard configuration |
DPSSLaser; 20HZ,70 mJ (1064), 35 mJ (532 nm), 12 mJ (266 nm)1) |
Optional |
Double excitation DPSS, pulse energy >100 mJ, The frequency can reach 100 Hz2) |
|
Spectrometer anddetector |
Standard configuration |
Echelle + EMCCD, 20 Hz, 200-1000 nm,The resolution capability can reach up to 60000 λ/Δ λ3) |
Optional |
Czerny-Turner/Echelle + ICCD/iStar SCMOS/CMOS,The frequency can reach 100 Hz (1 kHz in ROI)4)) |
|
Digital delayGenerator |
passageway |
8There are two SMB output channels and two SMB universal I/O channels8 SMB output |
pattern |
Single pulse, continuous, external triggering, gate control, load cycling, etc |
|
parameter |
Time resolution of 10 ns, accuracy of 5 ns, output of 3.3/5V |
|
Gas module |
Air pressure regulation |
1-1300 mbarAdjustable range, capable of introducing Ar/He protective gas |
Blowing system |
Continuous blowing mode; Pulse triggered purge mode |
|
Suction system |
Active gas/dust extraction system, filter can be replaced |
|
Compact version specifications |
Length x Width x Height |
1320 × 850 × 1500 mm |
weight |
300 kg |
1)Multiple frequency options available; 2) Depending on the laser model; 3) Depending on the configuration of the spectrometer; 4) Depends on ROI
LIBSTechnical principles and advantages
DragonFlyApplication case:
1. LIBSThe application of technology in cancer detection:
CEITECThe Lightigo research team at Brno University of Technology is conducting research on skin cancer detection using LIBS technology - the elemental composition of cancerous cells is different from that of normal cells, so LIBS technology is used to detect the elemental characteristics of tumor tissue for medical diagnosis.
This image is quoted from the news article of this interview on the Czech Radio website
2020On January 24th of the year, Czech radio released an interview with the Lightigo team at the Laser Spectroscopy Laboratory of Brno University of Technology. Pavel Po, the project leader of LightigořízkaSpeaking of: "LIBS measurement can obtain a series of element distribution images, helping pathologists to diagnose as soon as possible. Large tumors are easy to detect, but LIBS technology will be very useful for small satellite tumors that are difficult to detect
2. Mapping analysis of nano silver particle distribution in the roots of broad bean seedlings using dual excitation LIBS technology
Roots play an important role in providing nutrients to plants and protecting them from excessive metal ion toxicity. However, the difficulty of elemental analysis in roots is much greater than that in stem tissues, due to the fact that roots are usually much smaller than stems and shoots; The dry matter content is much lower, which brings great inconvenience to sample cutting; Usually, the relative content of the elements to be analyzed is relatively low; How to maintain the structural shape of soft and juicy samples to obtain the correct distribution of elements is also a challenge.
LightigoIn response to the above challenges, a successful exploration was conducted in this case by applying dual excitation LIBS technology to map and analyze nano silver particles (diameter 21.7 ± 2.3 nm) in the roots of broad bean seedlings. The goal is to detect elements in plant tissues in their natural state, achieving high mapping resolution while ensuring detection sensitivity. This is also the first attempt in the entire LIBS field to investigate the distribution of nanoparticles in plant roots.
Cu+Mapping results of root cross-sections of broad bean seedlings treated with solution at different resolutions: 100 μ m, 75 μ m, 50 μ m
Cu2+、 Microscopic images and elemental mapping corresponding results of root cross-sections of broad bean seedlings treated with Ag+and AgNPs for 7 days
Different concentrations of Cu2+Solution [a] 100 μ mol/l−1Cu2+;b)50 μmol l−1Cu2+;c) 10μmol l−1Cu2+; d) 0 μmol l−1Cu2+】Processing the mapping results of root cross-sections of broad bean seedlings; e) Characteristic spectral lines in the sample area; f)Cu2+As the concentration decreases, the corresponding spectral line intensity also decreases in sequence
Experimental conclusion:
LIBSFast technical testing speed; Even for roots with a diameter of only 2mm, mapping analysis can be performed on the distribution of metal ions and metal nanoparticles in their cross-section, with detection accuracy and image resolution sufficient to meet experimental requirements. By applying dual excitation technology, the mapping resolution can reach 50 μ m, which is sufficient to distinguish the distribution characteristics of elements in the root epidermis, cortex, and central column.
In addition, a short processing time of 7 days can detect the results, indicating that LIBS element mapping is also an effective experimental method for detecting element distribution in plants under natural environment and nutrient conditions. Therefore, it will be useful in the fields of plant physiology and environmental toxicology.
Quoted from: Krajcarov á L, Novotný K, Kummerová M, J. Dubová J, Gloser V, Kaiser J. Mapping of the spatial distribution of silver nanoparticles in root tissues of Vicia faba by laser-induced breakdown spectroscopy (LIBS) [J], Talanta 173 (2017) 28–35.)
LightigoReference List for Team Part
http://www.eco-tech.com.cn/portal/article/index/id/682.html
http://www.eco-tech.com.cn/portal/article/index/id/683.html